I have also noticed that some of my T's would eat all or some off their
Exuvia
... I always amused that it might be because they have not eaten while in premolt, since they might be hungry... But I have noticed that the Brachypelma species I keep, are more likely to do so than the Poecilotheria in my collection... so the theories in the previous comments might be more on the mark.
I have also heard that it can be detrimental to a T's to eat its own exuvia...
Maybe the more experienced members can elaborate on this and I'm sure that Stan has some useful info for us on this topic.